carbanide,chloropaladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

A na-emepụta Palladium(II) Chloro complex [(C8H12)(Cl)Pd] site na nhazi dị n'etiti PdCl4 na molekul trans-(1R,5S)-cycloocta-1,5-diene site na njikọ dative. Ngwaahịa a na-esi na ya pụta nwere otu dienyl ligand nke ejikọtara na nke ọ bụla n'ime etiti ígwè anọ site na nhazi eta. Ihe mgbagwoju a nwere ike okpomọkụ dị elu n'ihi ike intermolecular siri ike n'ime nhazi ahụ. Ngwa ya dị na usoro catalytic gụnyere mmeghachi omume njikọ cross. Dịka ọmụmaatụ, ụdị a na-eme ka nhazi njikọ C-C dị mfe n'oge Mmeghachi omume Njikọ Suzuki nke gụnyere ijikọ atọm carbon a gwakọtara agwakọta sp2 site na iji boronic acid dị ka nucleophiles. Njikọ ọhụrụ sitere na ya na-eme ka njirimara nke ihe eji eme ihe na ngwaọrụ eletrọnịkị si otú a na-eme ka ha dịkwuo irè. Ọzọkwa, ihe mkpali a na-achọta ngwa na mmeghachi omume njikọ Sonogashira ebe a na-ejikọ atọm a gwakọtara agwakọta sp site na iji alkynes terminal na-eduga na ịmepụta njikọ C-C si otú a na-emepụta otu ọrụ ọhụrụ nwere ike itinye n'ọrụ dị iche iche gụnyere mmepụta ọgwụ na sayensị ihe.