Trifluoromethanesulfonicacidtert-butyldimethylsilylester CAS:69739-34-0

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester, nke a na-akpọkarị TMSOTf, na-achọta ọtụtụ ojiji na kemịkalụ organic na sayensị ihe. Otu isi ojiji nke ngwakọta a bụ dị ka ihe na-agbanwe agbanwe na njikọta organic maka nchekwa nke otu hydroxyl na ihe ndị sitere na mmanya. A na-eji TMSOTf eme ihe na nkwadebe nke molekul dị mgbagwoju anya, ihe ndị na-eme ka ọgwụ dị n'etiti, na polymers na-arụ ọrụ site na ikpuchi ọrụ hydroxyl na ime ka mgbanwe ndị a na-achịkwa. Na kemịkalụ ọgwụ, TMSOTf na-arụ ọrụ dị mkpa na mmepe nke ndị na-achọ ọgwụ ọhụrụ na ihe ndị na-arụ ọrụ bioactive. Ike nke ngwakọta ahụ iji gbanwee otu ọrụ na molekul organic na-enye aka na njikọta nke ndị na-ahụ maka ọgwụ ike nwere akụrụngwa ọgwụ ka mma na mbelata mmetụta ọjọọ. Ọzọkwa, a na-eji TMSOTf eme ihe n'ọhịa nke kemịkalụ polymer maka ịrụ ọrụ nke elu polymer na mgbanwe nke agbụ polymer. Mmeghachi omume ya na-enye ohere maka njikwa ziri ezi na nhazi polymer, na-eduga na mmepụta nke ihe nwere ihe onwunwe ahaziri ahazi dịka nrapado, mmiri mmiri, na nkwụsi ike okpomọkụ. Na ụlọ ọrụ semiconductor, a na-eji TMSOTf eme ihe na imepụta ihe nkiri dị gịrịgịrị na nanostructures maka ngwaọrụ eletrọniki. Ndakọrịta nke ihe mejupụtara ya na ihe ndị e ji silicon mee na-eme ka o kwe omume itinye akwa ọrụ nwere ọkpụrụkpụ na ihe ndị dị n'elu ya, nke dị mkpa maka mmepe nke ihe eletrọnịkị dị elu na akụkụ optoelectronic. Na mgbakwunye, TMSOTf na-eje ozi dị ka ihe na-akpali akpali na ụfọdụ mmeghachi omume organic, na-akwalite nhazi nke njikọ carbon-carbon na carbon-heteroatom. Ọrụ catalytic ya na-eme ka mgbanwe sịntetik dị ngwa ma na-eme ka njikọta nke ihe owuwu molekul dị mgbagwoju anya dị mfe n'ọhịa nke mmepụta ngwaahịa eke, imewe ihe, na nyocha kemịkalụ. N'ozuzu, Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester na-egosipụta ọtụtụ ihe na uru dị ka ihe na-akpali akpali na ihe na-akpali akpali na mmepụta organic, mmepe ọgwụ, sayensị ihe, na teknụzụ semiconductor, na-egosipụta mkpa ọ dị n'ịkwalite nnyocha sayensị na ngwa ụlọ ọrụ.